1. Quiz (1): Second year student, Chemistry-Physics group
  2.  
  3. Twenty-five milliliters of a 0.1123 M solution of HCl are diluted in a 100.0 mL volumetric flask. A solution containing sodium hydroxide (MW=40.00 g/mol) requires 25.76 mL of the dilute HCl for neutralization. How many milligrams of NaOH are in the sodium hydroxide solution?

(5)

  1. You are required to manufacture a 5.0 ppm (w/v) solution of NaOH. How much NaOH (mg) must be placed in a 100.0 mL volumetric flask to make this solution?

(3)

  1. What volume of 0.01227 M HCl would be required to titrate 25.00 mL of the solution manufactured in the previous question?

(5)

  1. What Na2CO3 mass (MW=105.9 g/mole) is required to neutralize 22.31 mL of 0.1017 M HCl? What type of indicator would you use for this titration? Why?

(7)

  1. 5.3573 grams of Na2CO3 (MW=105.9 g/mole) are placed in a 1.0 L volumetric flask. A 25.00 mL aliquot of this solution is neutralized with 11.55 mL of HCl. What is the molarity of the HCl solution?

(5)

  1. A 0.3731 g mass of EDTA (MW = 372.240 g/mol) is made up to volume in a 100.0 mL volumetric flask. Calculate MEDTA through molecular weight.

(2)

  1. A solution of sodium thiosulfate was standardized using 0.2210 g of potassium iodate (MW = 214.00 g/mol) in water with excess KI and HCl for acidification. The liberated I2 was titrated with 41.64 mL of sodium thiosulfate.
    1. Show the reaction equations involving iodine liberation and subsequent thiosulfate titration.

(4)

    1. Calculate Mthio.

(5)

  1. A mass of 2.210 g KBrO3 (MW = 167.001 g/mol) is placed in a 250.0 mL volumetric flask. A 10.00 mL aliquot is removed and placed in 100 mL of water containing excess KI and acid. The liberated iodine requires 23.32 mL of thiosulfate for complete reaction. 
    1. Calculate Mthio.

(6)

    1. What indicator is used for this titration?  Describe the indicator colour before titration point is reached and why (how) this colour is generated.

(3)

    1. Why is important to add the indicator just before reaction is complete?

(1)