ahmedabudief

Dr. Ahmed Mohammed Abu-Dief Mohammed

Assistant Professor - Assistant professor of Inorganic and Physical Chemistry

Faculty of science

Address: Behind hospital of Sohag University - Ali Ebn Abi Taleb Street

117

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Hydrothermal preparation and characterization of ZnFe2O4 magnetic nanoparticles as  catalyst for the synthesis of multi‐substituted imidazoles
Nanoparticles are key focus of research for a wide range of novel applications. As such, ZnFe2O4 magnetic nanoparticles were synthesized hydrothermally and characterized via scanning and transmission electron microscopies, powder X‐ray diffraction, energy‐dispersive X‐ray and infrared spectroscopies, thermogravimetric analysis and magnetic measurements. They were used as a robust catalyst for the synthesis of a series of biologically active multi‐substituted imidazoles ... Read more

Synthesis, theoretical investigations, biocidal screening, DNA binding, in vitro cytotoxicity and molecular docking of novel Cu (II), Pd (II) and Ag (I) complexes
Three new Cu(II), Pd(II) and Ag(I) complexes with bi-dentate Schiff base ligand "HL" namely 2-[(4-Chloro-benzylidene)-amino]-phenol were synthesized. The stoichiometric ratios and physicochemical properties of these complexes were determined using elemental analyses (C, H, and N), magnetic measurements, IR, UV-Vis spectra, molar conductivity and thermal analyses. The results revealed that the metal ions coordinated with ligand HL through azomethine nitrogen and ... Read more

2018 | Keywords Therapy, Diabetes , complexes, vanadium,
Diabetes Mellitus Therapy
The concept of using metal ions for the remediation of diabetes generates from the report in 1899. A number of transitional and coordination compounds such as vanadium, chromium, manganese,cobalt, copper, zinc, tungsten and molybdenum have been suggested as possible adjuncts in the remediation of diabetes mellitus in vivoandin vitro. Metal compounds induce hypoglycemia by a wide diversity of mechanisms. Potential ... Read more

Disposal of Heavy Transition Cd(II) ions from Aqueous Solution utilizing Nano Sized Flamboyant Pod (Delonix regia)
The absorption of toxic heavy metal by natural adsorbents from water were indicated by investigation the effect of nano sized (_Delonix regia _(DR)) and (CADR) citric acid_ Delonix regia_ chemically modified adsorbent for removing the Cd2+ ions. Different techniques were employed for characterizing the adsorbent (_Delonix regia_) such energy dispersive analysis of X-ray (EDAX), Fourier transform infrared spectroscopy (FT-IR), Transmission ... Read more

Design,  Synthesis, Structure Inspection,  Biological Screening,  and DNA Binding Study of  Some New VO(II), Pd (II) and Ag(I)  Chelates incorporating Tri-dentate Chemo Sensor Imine Ligand
The present study was conducted to synthesis of some new imine VO(II), Pd(II) and Ag(I) complexes derived from 2-[(2-Hydroxy-naphthalen-1-ylmethylene)-amino]-benzoic acid were synthesized. The prepared imine ligands were analyzed by their melting point, IR, 1H NMR and 13C NMR spectroscopy. The investigated imine complexes were characterized by elemental analysis, FT IR, Uv-vis and thermal analysis (TGA) in air from ambient temperature ... Read more

Catalytic Oxidation of Benzyl Alcohol using Nanosized Ni/Cu  Schiff-Base Complexes and their Metal Oxides Nanoparticles
Three novel nanosized Cu and Ni Schiff-base complexes (ahpvCu, ahpnbCu, and ahpvNi) incorporating imine ligands derived from the condensation of 2-amino-3-hydroxypyridine with either 3-methoxysalicylaldehyde or 4-nitrobenzaldehyde were synthesized by a sonochemical approach. The structure of the ligands and their complexes was confirmed by IR, NMR spectroscopy, electronic spectra, elemental analysis, TGA, molar conductivity, and magnetic moment analyses. The results revealed ... Read more

Adsorption of the heavy metal ions onto biosorbents: A review
Heavy metal pollution in result of human activities such as mining has become a critical environmental issue nowadays. Various methods for removing heavy metal from industrial wastewater have been investigated. This paper reviews an economic and environment friendly process known as biosorption. Biosorption is a potential alternative to the conventional treatment processes such as adsorption on activated carbon. Some factors ... Read more

Some New  Ag(I),  VO(II)  and Pd(II) Chelates encompassing Tri-dentate Imine Ligand: Design, synthesis, Structure elucidation and DFT calculations for DNA Interaction, Antimicrobial, Anticancer Activities and Molecular Docking Studies
Some new complexes derived from VO(II), Ag(I) and Pd(II) metal ions and HNA imine ligand (L) _i.e. _(2-[(6-Allylidene-2-hydroxy-cyclohexa-1,3-dienylmethylene)-amino]-benzoic acid) have been prepared and their structures are elucidated _via_ molar conductance, elemental analyses, IR, NMR, magnetic susceptibility estimations and electronic spectral studies. Moreover, stability constants of the synthesized complexes were evaluated utilizing spectrophotometric technique. On the basis of molar conductance and ... Read more

Carbon steel pipelines corrosion inhibition by some novel imines during acidizing treatment of oil wells: Electrochemical and quantum chemical studies
The corrosion protection of the equipments and vessels is one of chief concerns of the maintenance and design engineers. From this point of view, three novel imine compounds were prepared and their structures were characterized by X-ray, 13C-NMR, 1H-NMR, mass, UV-Vis, FT-IR, spectral data and elemental analyses. The corrosion inhibition of the investigated inhibitors towards carbon steel in 15% HCl ... Read more

Synthesis, Characterization and Biological Studies of Some new Cr(III), Fe(III) and Cu(II) Complexes based on Multi-Substituted  Aryl Imidazole ligand
New Cr (III), Fe (III) and Cu (II) complexes with MSBB (2‐(1‐butyl‐4,5 diphenyl‐1H‐imidazol‐2‐yl)(4-bromophenol) were synthesized. The multi-substituted aryl imidazole ligand (MSBB) and its complexes were characterized by using elemental and thermal analysis, molar conductivity, magnetic susceptibility, UV-Vis spectral data, IR, and NMR. The obtained data showed that prepared complexes were 1 :1 (metal : ligand) ratio, octahedral (Oh) for all ... Read more