ahmedabudief

Dr. Ahmed Mohammed Abu-Dief Mohammed

Assistant Professor - Assistant professor of Inorganic and Physical Chemistry

Faculty of science

Address: Behind hospital of Sohag University - Ali Ebn Abi Taleb Street

118

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Some new nano-sized Cr(III), Fe(II), Co(II), and Ni(II) complexes: Structural characterization, electrochemical, antioxidant, antimicrobial, antiviral assessment and DNA interaction
To estimate the biological preference of synthetic small drugs towards DNA target, new metal based chemotherapeutic agents of nano-sized Cr(III), Fe(II), Co(II) and Ni(II) Schiff base complexes having N,N,O donor system were synthesized and thoroughly characterized by physic-chemical techniques. The redox behavior of the Cr(III), Fe(II) and Co(II) complex was investigated by electrochemical method using cyclic voltammetry. IR results proven ... Read more

Some New Nano-sized Mononuclear Cu(II) Schiff Base Complexes: Design, Characterization, Molecular Modeling and Catalytic Potentials in Benzyl Alcohol Oxidation
In the present contribution, some novel Cu(II) complexes were synthesized from tri- and tetradentate imine ligands. All the prepared compounds were elucidated by different physicochemical methods. Density Functional Theory calculations were carried out to explain the equilibrium geometry of the bsisnph and npisnph ligands and their Cu(II) complexes. Interaction of the synthesized ligands with Cu(II) affords nano-sized particles via TEM. ... Read more

Effect of chromium substitution on the structural and magnetic properties of nanocrystalline zinc ferrite
Single-phase Cr doped zinc ferrites have been synthesized by hydrothermal method. The crystal structure, microstructure, crystallite size and distribution, composition and magnetic properties of the synthesized nanoparticles were determined using X-ray powder diffraction, electron microscopies and vibrating sample magnetometry. Powders are composed of ultrafine spherical nanoparticles with a highly homogeneous elemental composition. The nanoparticles have partially inversed cubic spinel structure ... Read more

Synthesis, structure elucidation, biological screening, molecular modeling and DNA binding of some Cu(II) chelates incorporating imines derived from amino acids
Three tridentate Schiff bases amino acids were prepared by direct condensation of 3-methoxysalicylaldehyde (MS) or 4-diethylaminosalicylaldehyde (DS) with α-amino acid ligands [l-phenylalanine (P), l-histidine (H) and DL-tryptophan (T)]. The prepared Schiff bases amino acids were investigated by melting points, elemental analysis, 1HNMR and 13CNMR, IR, UV–Vis spectra, conductivity and magnetic measurements analyses. Subsequently, copper was introduced and Cu(II) complexes formed. ... Read more

Removal of Toxic Pb(II) Ions from Aqueous Solution by Nano Sized Flamboyant Pod (Delonix regia)
The removing of toxic heavy metals from aqueous solution by agricultural biosorbents was investigated by studying the effect of nano sized (Delonix regia) and chemically modified biosorbent citric acid Delonix regia (CADR) for removing of Pb2+ ions. TEM, XRD and EDS, FT-IR, SEM methods were used for characterizing the biosorbent(Delonix regia). The effect of contact time, pH,temperature, dosage of biosorbent, ... Read more

Physicochemichal properties, DNA interaction, antiviral and antioxidant activities of some Amino Acid Imine Chelates
Schiff base amino acid ligands which derived from the condensation of 3-methoxysalicylaldehyde (MS) or 4-diethylaminosalicylaldehyde (DS) with some of α-amino acids (Phenylalanine (Phe), Histidine (His), Tryptophan (Trp)) were prepared. Moreover, eleven Schiff base amino acid binary Fe(II) and Cu(II) complexes were prepared. In addition to, five ternary Cu(II) complexes which derived from the prepared Schiff base amino acid ligands as ... Read more

Nano Sized Moringa oleifera an Effective Strategy for Pb(II) ions Removal from Aqueous Solution
Nano-sized _Moringa oleifera_ is considered an effective biosorbent with high surface area from agricultural waste, low coast and environment-friendly which can be used for removal of Pb2+ from waste water. Thus our study stem to investigate the ability of natural nano-sized biosorbents for removing very toxic Pb2+ ions from aqueous solution. The investigated biosorbent (_Moringa oleifera_)was characterized by FTIR, SEM, ... Read more

Desighn, Characterization and Biological activity of new mixed ligand transition metal complexes of glutamine, glutaric and glutamic acid with nitrogen based ligands.
A new series of Cu(II), Co(II), Ni(II) and Fe(II) ternary complexes of glutamine, glutaric and glutamic acid with imidazole derivatives have been synthesized. The nature of bonding and the stereochemistry of the complexes have been deduced from elemental analyses, infrared, electronic spectra, conductivity measurements and thermogravimetric analysis. The structure of [Co(glu)(IMI)2] and [Fe(glu)(IMI)2(H2O)2] complexes was validated using quantum mechanics calculations ... Read more

Nano sized ternary Cu(II) complexes Encompassing Salicylaldehyde Derivatives and Amino Acids as an Effective Strategy for Antimicrobial Activity Improvement and DNA Interaction
A series of ternary Cu(II) complexes encompassing ONO donor Schiff base amino acid ligands were synthesized from condensation of 3–methoxysalicylaldehyde (MS) or 4-diethylamino salicylaldehyde (DS) with α-amino acids (L-phenylalanine (Phe), L-histidine (His), DL-tryptophan (Trp)) as primary ligand and 2, 4-bipridyl (DP) as secondary ligand. All the prepared compounds were characterized by melting points, decomposition temperatures, elemental analysis, UV-Vis, IR spectra, ... Read more

Removal of Cd(II) ions From Aqueous Solution using Nano sized Moringa Oleifera
This research aims to study the effect of nano sized _Moringa oleifera_ on adsorption of Cd2+ ions from aqueous solution. The investigated biosorbent was characterized by FTIR, SEM, TEM, XRD and EDS techniques. The influence of pH, temperature, adsorbent dosage, contact time, metal ion concentration and chemical treatment of biomass were investigated. The maximum capacity (qm) of Cd2+ ions biosorption ... Read more