ahmedabudief

Dr. Ahmed Mohammed Abu-Dief Mohammed

Assistant Professor - Assistant professor of Inorganic and Physical Chemistry

Faculty of science

Address: Behind hospital of Sohag University - Ali Ebn Abi Taleb Street

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Synthesis, catalysis, antimicrobial activity and DNA interactions of new Cu(II)-Schiff base complexes
Structural features and catalytic activities of five ternary copper (II)-Schiff base complexes are investigated. The ligands are derived from 3–methoxysalicylaldehyde (MS) or 4– diethylaminosalicylaldehyde (DS) and amino acids {L-phenylalanine (Phe), L histidine (His) or DL-tryptophan (Trp)}, as primary ligands, and 2,4’-bipyridyl (DP) as secondary ligand. Cu(II)- complexes are characterized by various physicochemical tools. The catalytic efficiency of Cu(II)-complexes is studied ... Read more

Facile Synthesis and Characterization of Novel Gd2O3/CdO Binary Mixed Oxide Nanocomposites
In this study, pure cadmium oxide (CdO) nanoparticles as well as a mixed gadolinium oxide (Gd2O3)/CdO nanocomposites with mixing contents (0% ≤ Gd2O3 content ≤ 15%) were synthesized via facile precipitation technique followed by calcined treatment. The synthesized nano-powders were characterized by various techniques in terms of their structure, morphology, composition, and optical properties. X-ray diffraction analysis illustrated that all ... Read more

Design, Synthesis and Structural Inspection of Some Novel Di- And Tri-Azomethene Compounds as Chemo Sensors for the Detection of Various Metal Ions
In this study, NBA imine compound was synthesized via an easy one-pot condensation of 3-nitro-benzaldyhide with 2-amino benzoic acid in 1:1 ratio and DAPH imine compound derived from 2,6-diacetyl pyridine and phenyl hydrazine hydrochloride. Consequences of the newly synthesized compounds hooked up with the aid of FT-IR, elemental analyses, 13C-NMR ,1H-NMR and digital spectral research. Experiments had been consistent with ... Read more

A Simple and Reliable Synthesis of Superparamagnetic Magnetite Nanoparticles by Thermal Decomposition of Fe(acac)3
Magnetic nanoparticles have been largely proposed as means of technological tools due to its value in different fields, especially in biomedicine. Herein, we present a robust, highly reproducible and low-cost method to obtain superparamagnetic magnetite nanoparticles (MNP-II) of about 15±5 nm diameter by thermal decomposition of [Fe(acac)3] in a one pot, two steps method. In the first step, magnetite nanoparticles ... Read more

A robust in vitro Anticancerc, Antioxidant and Antimicrobial Agents Based on New Metal-Azomethine Chelates Incorporating Ag(I),  VO(II)  and Pd(II) Cations: Probing the Aspects of DNA Interaction
A novel azomethine ligand (HNAP) [HNAP = 1-(Pyridin-3-yliminomethyl)-naphthalen-2-ol] and its Ag(I), Pd(II) and VO(II) chelates have been synthesized and structurally inspected using a wide range of spectroscopic and analytical tools, including infra-red (IR), ultraviolet-visible (UV-Vis) and 1H NMR spectroscopy techniques, CHN analysis, molar conductance, magnetic susceptibility, and thermogravimetric analysis. The molar conductance measurements reveal that the chelates are non-electrolytes. The ... Read more

Synthesis and Characterization of New Cr(III), Fe(III) and Cu(II) Complexes Incorporating Multi-Substituted Aryl Imidazole Ligand: Structural, DFT, DNA Binding, and Biological Implications
Designing new metal-based molecular antibiotics is an efficient approach to overcome the growing threat of antimicrobial resistance. In this paper, novel Cr(III), Fe(III) and Cu(II) complexes comprising substituted aryl imidazole ligand (MSEB), namely (2-(1-(2-hydroxyethyl)-4,5-diphenyl-1H-imidazole-2-yl)(4-bromophenol)) have been synthesized and characterized using infra-red (IR), ultraviolet-visible (UV-Vis) and 1H, 13C NMR spectroscopic techniques, together with elemental (CHN) and thermogravimetric analyses, molar conductance, and ... Read more

Impact of Co2+ substitution on microstructure and magnetic properties of CoxZn1-xFe2O4 nanoparticles
In the present work, we synthesized CoxZn1-xFe2O4 spinel ferrite nanoparticles (x= 0, 0.1, 0.2, 0.3 and 0.4) via the precipitation and hydrothermal-joint method. Structural parameters were cross-verified using X-ray powder diffraction (XRPD) and electron microscopy-based techniques. The magnetic parameters were determined by means of vibrating sample magnetometry. The assynthesized CoxZn1-xFe2O4 nanoparticles exhibit high phase purity with a single-phase cubic spineltype ... Read more

The synthesis of CuO and NiO nanoparticles by facile thermal decomposition of metal-Schiff base complexes and an examination of their electric, thermoelectric and magnetic Properties
In this study, CuO and NiO NPs have been synthesized by facile thermal decomposition of Schiff base complexes and their physical properties have been examined. The synthesized CuO and NiO NPs are crystallized in polycrystalline monoclinic and cubic structures with average particle size 17 ± 0.4 and 62 ± 1 nm, respectively. The electrical conductivity measurements confirm that the conduction ... Read more

Electric, Thermoelectric and Magnetic Properties of Nickel(II) Imine Nanocomplexes
Production of novel organic semiconductor nanomaterials is essential for enabling the development of personal, portable and flexible electronic modules. This work presents Ni(II)-Schiff base complexes with enhanced Seebeck coefficient and weak ferromagnetic ordering for thermoelectric and magnetic devices. Four Ni(II)-Schiff base complexes (namely [Ni(C12">1212H10">1010N3O4Br)]⋅">⋅⋅2H2O, [Ni(C16">1616H11">1111N3O4)">4)4)]⋅">⋅⋅2H2O, [Ni(C21">2121H14">1414N5O8Br)] and [Ni(C25">2525H17">1717N5O8)">8)8)]⋅1/2">⋅1/2⋅1/2H2O) have been synthesized in nanosized dimensions. The electrical and thermoelectric properties have ... Read more

The electric and thermoelectric properties of Cu(II)-Schiff base nano-complexes
have been widely investigated. However, their thermoelectric (TE) properties remain unreported. This work presents Cu(II)-Schiff base complexes as promising materials for TE power generation. Therefore, three Cu(II)-Schiff base complexes (namely, [Cu(C32H22N4O2)].3 2H2O, [Cu(C23H17N4O7Br)], and [Cu(C27H22N4O8)].H2O) have been synthesized in nanosized scale. The electric and TE properties have been studied and comprehensive discussions have been presented to promote the nano-complexes (NCs) ... Read more