ahmedabudief

Dr. Ahmed Mohammed Abu-Dief Mohammed

Assistant Professor - Assistant professor of Inorganic and Physical Chemistry

Faculty of science

Address: Behind hospital of Sohag University - Ali Ebn Abi Taleb Street

117

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Electric, Thermoelectric and Magnetic Properties of Nickel(II) Imine Nanocomplexes
Production of novel organic semiconductor nanomaterials is essential for enabling the development of personal, portable and flexible electronic modules. This work presents Ni(II)-Schiff base complexes with enhanced Seebeck coefficient and weak ferromagnetic ordering for thermoelectric and magnetic devices. Four Ni(II)-Schiff base complexes (namely [Ni(C12">1212H10">1010N3O4Br)]⋅">⋅⋅2H2O, [Ni(C16">1616H11">1111N3O4)">4)4)]⋅">⋅⋅2H2O, [Ni(C21">2121H14">1414N5O8Br)] and [Ni(C25">2525H17">1717N5O8)">8)8)]⋅1/2">⋅1/2⋅1/2H2O) have been synthesized in nanosized dimensions. The electrical and thermoelectric properties have ... Read more

The electric and thermoelectric properties of Cu(II)-Schiff base nano-complexes
have been widely investigated. However, their thermoelectric (TE) properties remain unreported. This work presents Cu(II)-Schiff base complexes as promising materials for TE power generation. Therefore, three Cu(II)-Schiff base complexes (namely, [Cu(C32H22N4O2)].3 2H2O, [Cu(C23H17N4O7Br)], and [Cu(C27H22N4O8)].H2O) have been synthesized in nanosized scale. The electric and TE properties have been studied and comprehensive discussions have been presented to promote the nano-complexes (NCs) ... Read more

Synthesis, characterization and photocatalysis enhancement of Eu2O3-ZnO mixed oxide nanoparticles
Pure ZnO nanoparticles (NPs) and mixed Eu2O3 and ZnO NPs with different Eu2O3 ratios (5%, 10%, and 15%) were synthesized by a precipitation method under optimum conditions. The synthesized samples were characterized by means of X-ray diffraction, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy, transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, and UV–vis diffuse reflectance spectroscopy. ... Read more

Functionalization of Magnetic Nanoparticles for Drug Delivery
Magnetic nanoparticles (MNPs) possess unique magnetic properties and the ability to function at the cellular and molecular level of biological interactions making them an attractive platform as carriers for drug delivery. Recent advances in nanotechnology have improved the ability to specifically tailor the features and properties of MNPs for these biomedical applications. To better address specific clinical needs, MNPs with ... Read more

Electric, thermoelectric and magnetic characterization of γ-Fe2O3 and Co3O4 nanoparticles synthesized by facile thermal decomposition of metal-Schiff base complexes
Using novel compounds for synthesis of metal oxide nanomaterials can tune their physical properties due to the associated variation in the shape, size and crystallinity. In this work, γ-Fe2O3 and Co3O4 nanoparticles were successfully prepared by a facile thermal decomposition route, employing [Fe(C32H22N4O2)]·2H2O and [Co(C16H11N3O4)].12">12H2O complexes, respectively as new precursors. The x-ray diffraction and high resolution transmission electron microscopy investigation ... Read more

Sonochemical synthesis, structural inspection and semiconductor behavior of three new nano sized Cu(II), Co(II) and Ni(II) chelates
Three novel nanosized Cu(II), Co(II) and Ni(II) complexes of imine ligand attained from the condensation of 2‐amino‐3‐hydroxypyridine and 3‐methoxysalicylaldehyde have been prepared and investigated using diverse chemical methods such as NMR, CHN analysis, conductance, IR, Spectral studies, TGA and magnetic moment measurements. The obtained data confirmed that the synthesized complexes have metal: ligand ratio of 1:1 and octahedral geometry for ... Read more

Hydrothermal preparation and characterization of ZnFe2O4 magnetic nanoparticles as  catalyst for the synthesis of multi‐substituted imidazoles
Nanoparticles are key focus of research for a wide range of novel applications. As such, ZnFe2O4 magnetic nanoparticles were synthesized hydrothermally and characterized via scanning and transmission electron microscopies, powder X‐ray diffraction, energy‐dispersive X‐ray and infrared spectroscopies, thermogravimetric analysis and magnetic measurements. They were used as a robust catalyst for the synthesis of a series of biologically active multi‐substituted imidazoles ... Read more

Synthesis, theoretical investigations, biocidal screening, DNA binding, in vitro cytotoxicity and molecular docking of novel Cu (II), Pd (II) and Ag (I) complexes
Three new Cu(II), Pd(II) and Ag(I) complexes with bi-dentate Schiff base ligand "HL" namely 2-[(4-Chloro-benzylidene)-amino]-phenol were synthesized. The stoichiometric ratios and physicochemical properties of these complexes were determined using elemental analyses (C, H, and N), magnetic measurements, IR, UV-Vis spectra, molar conductivity and thermal analyses. The results revealed that the metal ions coordinated with ligand HL through azomethine nitrogen and ... Read more

2018 | Keywords Therapy, Diabetes , complexes, vanadium,
Diabetes Mellitus Therapy
The concept of using metal ions for the remediation of diabetes generates from the report in 1899. A number of transitional and coordination compounds such as vanadium, chromium, manganese,cobalt, copper, zinc, tungsten and molybdenum have been suggested as possible adjuncts in the remediation of diabetes mellitus in vivoandin vitro. Metal compounds induce hypoglycemia by a wide diversity of mechanisms. Potential ... Read more

Disposal of Heavy Transition Cd(II) ions from Aqueous Solution utilizing Nano Sized Flamboyant Pod (Delonix regia)
The absorption of toxic heavy metal by natural adsorbents from water were indicated by investigation the effect of nano sized (_Delonix regia _(DR)) and (CADR) citric acid_ Delonix regia_ chemically modified adsorbent for removing the Cd2+ ions. Different techniques were employed for characterizing the adsorbent (_Delonix regia_) such energy dispersive analysis of X-ray (EDAX), Fourier transform infrared spectroscopy (FT-IR), Transmission ... Read more