ahmedabudief

Dr. Ahmed Mohamed Abu-Dief

Professor - Professor of Physical and Inorganic Chemistry

Faculty of science

Address: Behind hospital of Sohag University - Ali Ebn Abi Taleb Street

326

Like
20 103 262 149 5 107 7.8K 30.9K
275

Newly Added
  • Courses 20
  • Course Supplements 103
  • Courses Tasks 262
  • Publications 149
  • Office hours 5
  • Announcements 107
  • File uploaded 135
  • Downloaded Times 1298

Synthesis, characterization, DFT calculations and biological studies of Mn(II), Fe(II), Co(II) and Cd(II) complexes based on a tetradentate ONNO donor Schiff base ligand

2017 | Keywords DNA interaction, Arenes, Arene complexes, Schiff bases, Quantum chemical calculations, Biological studies,
Synthesis, characterization, DFT calculations and biological studies of Mn(II), Fe(II), Co(II) and Cd(II) complexes based on a tetradentate ONNO donor Schiff base ligand
This study highlights synthesis and characterization of a tetradentate ONNO Schiff base ligand namely (1, 1′- (pyridine-2, 3-dimethyliminomethyl) naphthalene-2, 2′-diol) and hereafter denotes as “HNDAP″ and selected metal complexes including Mn(II), Fe(II), Co(II) and Cd(II) as a central metal. HNDAP was synthesized from 1:2 M ratio condensation of 2, 3-diaminopyridine and 2- hydroxy-1-naphthaldhyde, respectively. The stoichiometric ratios of the prepared ... Read more

α-Bi2O3 nanorods: synthesis, characterization and UV-photocatalytic activity

2017 | Keywords XRD, SEM, α-Bi2O3, nanorods, TEM, FTIR, photocatalyst, characterization,
α-Bi2O3 nanorods: synthesis, characterization and UV-photocatalytic activity
In this study, Monoclinic bismuth oxide nanorods (_α_-Bi2O3 NRs) were successfully synthesized by a simple one-step hydrothermal route using (water: ethanol) (1:1) as a mixed solvents at optimum conditions. The Bi2O3 nano-powder was characterized in detail by different techniques in terms of their structural, morphological, compositional, optical and photocatalytic properties. X-ray diffraction (XRD) analysis indicated that the as-synthesized Bi2O3 NRs ... Read more

Synthesis, characterization, and biological activity of new mixed ligand complexes of glutamine, glutaric, and glutamic acid with nitrogen based ligands

2017 | Keywords Ternary complexes; imidazol; glutamine; glutamic acid; glutaric acid; CT-DNA, mixed ligand,
Synthesis, characterization, and biological activity of new mixed ligand complexes of glutamine, glutaric, and glutamic acid with nitrogen based ligands
A new series of Cu(II), Co(II), Ni(II), and Fe(II) ternary complexes of glutamine, glutaric, and glutamic acid with imidazole derivatives have been synthesized. The nature of the bonding and the stereochemistry of the complexes have been deduced from elemental analyses, infrared and electronic spectra, conductivity measurements, and thermogravimetric analysis. The structure of [Co(glu)(IMI)2] and [Fe(glu)(IMI)2(H2O)2] complexes was validated using quantum ... Read more

Corrosion inhibition of carbon steel pipelines by some novel Schiff base compounds during acidizing treatment of oil wells studied by electrochemical and quantum chemical methods

2017 | Keywords Carbon steel alloy, Corrosion inhibition, Schiff base compounds, EIS, SEM, Quantum chemical calculations, IR, NMR,
Corrosion inhibition of carbon steel pipelines by some novel Schiff base compounds during acidizing treatment of oil wells studied by electrochemical and quantum chemical methods
Three novel Schiff bases compounds were prepared and their structures were characterized by X-ray, 13C-NMR, 1H-NMR, mass, UV–Vis, FT-IR, spectral data and elemental analyses. The corrosion inhibition of the investigated inhibitors towards carbon steel in 15% HCl was investigated by using electrochemical measurements (EIS, LPR corrosion rate and Tafel plots), SEM, EDX and quantum chemical methods. The results showed that, ... Read more

Ni(II) and Cu(II) complexes : synthesis, spectroscopic characterization, theoretical calculations, DNA interaction and antimicrobial studies

2017 | Keywords electrophoresis, DNA interaction, TGA, DFT studies, asymmetric Schiff base ligand, IR, NMR, Antimicrobial activity,
Ni(II) and Cu(II) complexes : synthesis, spectroscopic characterization, theoretical calculations, DNA interaction and antimicrobial studies
A novel Schiff base, namely _Z_‐3‐((2‐((_E_)‐(2‐hydroxynaphthyl)methylene)amino)‐5‐nitrophenylimino)‐1,3‐dihydroindin‐2‐one, was synthesized from the condensation of 2‐hydroxy‐1‐naphthaldehyde and isatin with 4‐nitro‐_o_‐phenylenediamine. It was structurally characterized on the basis of 1H NMR, 13C NMR and infrared spectra and elemental analyses. In addition, Ni(II) and Cu(II) complexes of the Schiff base ligand were prepared. The nature of bonding and the stereochemistry of the investigated complexes were ... Read more

Kinetics, reactivity, initial-transition state analysis and thermodynamic parameters of base-catalyzed hydrolysis of coumalic acid in solvents with different polarities

2017 | Keywords Isokinetic temperature, Transition state, Initial state, Transfer chemical potential, Activation energy barrier, Base-catalyzed hydrolysis, Coumalic acid, Kinetics, aqueous-methanol, aqueous-acetone,
Kinetics, reactivity, initial-transition state analysis and thermodynamic parameters of base-catalyzed hydrolysis of coumalic acid in solvents with different polarities
Base-catalyzed hydrolysis of coumalic acid (COU) in binary aqueous-methanol and aqueous-acetone mixtures has been studied kinetically at a temperature range from 283 to 313 K. Moreover, the change in the activation energy barrier of COU from water to water–methanol and water–acetone mixtures is estimated from the kinetic data. Solvent effects on reactivity trends have been analyzed into initial and transition ... Read more

Hydrophobicity, reactivity trends of base catalyzed hydrolysis of some novel high spin Fe(II) chelates in some binary aqueous solvent mixtures: Initial-transition state analysis

2017 | Keywords Solvent, Hydrophobic, Hydrophilic, Kinetics, Hydration, Solvolysis, Reactivity, Initial state-transition state,
Hydrophobicity, reactivity trends of base catalyzed hydrolysis of some novel high spin Fe(II) chelates in some binary aqueous solvent mixtures: Initial-transition state analysis
Rate constants for the base hydrolysis of bis(naphthylidene alanate)iron (II) (nali), bis(naphthylidene phenylalanate)iron(II) (nphali), bis(naphthylidene aspartate)iron(II) (nasi), (naphthylidene histidinate)iron(II) (nhi), bis(naphthylidene arginate)iron(II) (nari) have been reported in different binary aqueous solvent mixtures at 298 K. The observed reactivity trends are discussed in terms of the hydrophilic and hydrophobic forms of the complexes investigated, as well as the transfer chemical potentials ... Read more

Design and Development of Some Novel Metal Anil Chelates for DNA Interaction and Pharmaceutical Applications

2017 | Keywords Development effects, Metal Anil Chelates, DNA interaction, Pharmaceutical Applications, Design,
Design and Development of Some Novel Metal Anil Chelates for DNA Interaction and Pharmaceutical Applications
Air and moisture stable coordination compounds of some first transition metals such as Cr (III), VO (II), Ni(II) and Mn(II) with newly designed tri- and tetra-dentate imine ligands (HNAP, HNPN and ESPN) were synthesized. Tridentate imine ligands (HNAP, ESAP) were synthesized by reacting 2-hydroxynapthaldehyde (HN) with 2-aminophenol (AP), whereas tetra-dentate imine ligands (HNPN and ESPN) were prepared by reacting 2-hydroxy-1-napthaldehyde ... Read more

Pharmaceutical Applications of Nano Imine Complexes and Their Oxides

2017 | Keywords Pharmaceutical, Oxides, nanoparticles, Imine complexes, TGA,
Pharmaceutical Applications of Nano Imine Complexes and Their Oxides
Some new nano-sized Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Cd(II), Zn(II),, Pb(II) and Ag(I) complexes with imine ligands derived from 2-amino-3-hydroxypyridine (ahp) and 3-methoxysalicylaldehyde (v) or 4-nitrobenzaldehyde (nb) were prepared by sonochemical method. Melting point, decomposition temperature, infrared (IR) and NMR spectra, elemental analyses, conductance and magnetic susceptibility measurements, TG and UV – Visible spectrophotometric studies were utilized in characterizing of ... Read more

Some Nano imine Chelates for DNA Binding and Biological Applications

2017 | Keywords TGA, Nano imine Chelates, DNA binding, Biological Applications,
Some Nano imine Chelates for DNA Binding and Biological Applications
Air and moisture stable coordination compounds of some first transition metals such as Cr (III), Fe (II), Co(II), Ni(II) and Cu(II) with newly designed tri and tetra-dentate imine ligands ( bsap, npap, bsisnph, npisnph) were synthesized. Tridentate imine ligands (bsap, npap) were synthesized by reacting 5-bromosalicyaldehyde (bs) or 2-hydroxy-1-napthaldehyde (np) with 2-aminopyridine (ap), whereas tetra-dentate imine ligands (bsisnph, npisnph) were ... Read more