refat.abdelhamid

Refat Abdel-Hamid Mahmoud

Professor - Professor

Faculty of science

Address: معمل الكيمياء الكهربية - الدور الثالث - كلية العلوم (المبنى الجديد) - جامعة سوهاج 82524 - سوهاج

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2013 | Keywords Caffeic acid,
Electrochemical behavior of antioxidants: Part 3. Electrochemical studies of caffeic Acid–DNA interaction and DNA/carbon nanotube biosensor for DNA damage and protection
Multi-walled carbon nanotubes-modified glassy carbon electrode biosensor was used for electrochemical studies of caffeic acid–dsDNA interaction in phosphate buffer solution at pH 2.12. Caffeic acid, CAF, shows a well-defined cyclic voltammetric wave. Its anodic peak current decreases and the peak potential shifts positively on the addition of dsDNA. This behavior was ascribed to an interaction of CAF with dsDNA giving ... Read more

2013 | Keywords Gallic acid,
Adsorptive Stripping Voltammetric Determination of Gallic Acid Using an Electrochemical Sensor Based on Polyepinephrine/glassy Carbon Electrode and its Determination in Black Tea Sample
An efficient adsorptive stripping voltammetric (AdSV) method for determination of gallic acid, GA, was developed by using an electrochemical sensor based on polyepinephrine/glassy carbon electrode, PEP/GCE. Modification of GCE with PEP was done by electropolymersation of epinephrine, EP, in 0.2 M phosphate buffer solution using cyclic voltammetry, cv. A well-defined redox cv wave of epinephrine in potential range of -0.10 ... Read more

2012 | Keywords Quercetin,
Electrochemical behaviour of antioxidants: Part 2. Electrochemical oxidation mechanism of quercetin at glassy carbon electrode modified with multi-wall carbon nanotubes
Electrochemical oxidation mechanism of quercetin was investigated at glassy carbon electrode modified with multi-wall carbon nanotubes in aqueous 0.2 M phosphate solutions with different pHs. The investigation was carried out using cyclic voltammetry, double potential step chronoamperometric and chronocoulometric techniques. It was found that the oxidation mechanism proceeds in sequential steps, related with the five-hydroxyl groups in the three aromatic ... Read more

2011 | Keywords Gallic acid,
Electrochemical behavior of antioxidants: I. Mechanistic study on electrochemical oxidation of gallic acid in aqueous solutions at glassy-carbon electrode
Mechanism of electrochemical oxidation of gallic acid in aqueous phosphate buffer solutions of different pH’s was studied at glassy-carbon electrode. The study was performed using cyclic, convolution–deconvolution sweep voltammetry, chronoamperometry and chronocoulometry. It gives two irreversible diffusion-controlled cyclic voltammetric waves at the entire range of pH. The electrochemical oxidation mechanism was proposed to be an ECEC-first order mechanism in which ... Read more

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