Desighn, Characterization and Biological activity of new mixed ligand transition metal complexes of glutamine, glutaric and glutamic acid with nitrogen based ligands.
A new series of Cu(II), Co(II), Ni(II) and Fe(II) ternary complexes of glutamine, glutaric and glutamic acid with imidazole derivatives have been synthesized. The nature of bonding and the stereochemistry of the complexes have been deduced from elemental analyses, infrared, electronic spectra, conductivity measurements and thermogravimetric analysis. The structure of [Co(glu)(IMI)2] and [Fe(glu)(IMI)2(H2O)2] complexes was validated using quantum mechanics calculations ... إقراء المزيد