Temperature and salt effects of the kinetic reactions of substituted 2-pyridylmethylene-8-quinolyl iron (II) complexes as antimicrobial, anti-cancer and antioxidant agents with Cyanide ions
Kinetics of substitution reaction of three high spin pyridylmethylene-8-quinolyl iron (II) complexes by CN- ions are studied spectophotometrically in various ratios of aqueous-methanol binary mixtures at 298 ± 0.2 K. Kinetics of the substitution reaction follow the rate law (k2[CN−][complex])on applying of the conditions of the pseudo-first-order. Reactivity of the reaction was investigated in terms of organic ligand moiety and ... إقراء المزيد