ahmedabudief

Dr. Ahmed Mohammed Abu-Dief Mohammed

Prof. Assistant - Assistant professor of Inorganic and Physical Chemistry

Faculty of science

Address: Behind hospital of Sohag University - Ali Ebn Abi Taleb Street

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Publications Which contain the keyword: TGA


Nano sized ternary Cu(II) complexes Encompassing Salicylaldehyde Derivatives and Amino Acids as an Effective Strategy for Antimicrobial Activity Improvement and DNA Interaction
A series of ternary Cu(II) complexes encompassing ONO donor Schiff base amino acid ligands were synthesized from condensation of 3–methoxysalicylaldehyde (MS) or 4-diethylamino salicylaldehyde (DS) with α-amino acids (L-phenylalanine (Phe), L-histidine (His), DL-tryptophan (Trp)) as primary ligand and 2, 4-bipridyl (DP) as secondary ligand. All the prepared compounds were characterized by melting points, decomposition temperatures, elemental analysis, UV-Vis, IR spectra, ... Read more

Synthesis, Characterization and Biological Studies of Some new Cr(III), Fe(III) and Cu(II) Complexes based on Multi-Substituted  Aryl Imidazole ligand
New Cr (III), Fe (III) and Cu (II) complexes with MSBB (2‐(1‐butyl‐4,5 diphenyl‐1H‐imidazol‐2‐yl)(4-bromophenol) were synthesized. The multi-substituted aryl imidazole ligand (MSBB) and its complexes were characterized by using elemental and thermal analysis, molar conductivity, magnetic susceptibility, UV-Vis spectral data, IR, and NMR. The obtained data showed that prepared complexes were 1 :1 (metal : ligand) ratio, octahedral (Oh) for all ... Read more

Some New  Ag(I),  VO(II)  and Pd(II) Chelates encompassing Tri-dentate Imine Ligand: Design, synthesis, Structure elucidation and DFT calculations for DNA Interaction, Antimicrobial, Anticancer Activities and Molecular Docking Studies
Some new complexes derived from VO(II), Ag(I) and Pd(II) metal ions and HNA imine ligand (L) _i.e. _(2-[(6-Allylidene-2-hydroxy-cyclohexa-1,3-dienylmethylene)-amino]-benzoic acid) have been prepared and their structures are elucidated _via_ molar conductance, elemental analyses, IR, NMR, magnetic susceptibility estimations and electronic spectral studies. Moreover, stability constants of the synthesized complexes were evaluated utilizing spectrophotometric technique. On the basis of molar conductance and ... Read more

2018-10-10 11:53:46 Keywords IR, imines, DNA binding, TGA, Chemo Sensor, VO(II), Pd (II), DFT, Conductivity,
Design,  Synthesis, Structure Inspection,  Biological Screening,  and DNA Binding Study of  Some New VO(II), Pd (II) and Ag(I)  Chelates incorporating Tri-dentate Chemo Sensor Imine Ligand
The present study was conducted to synthesis of some new imine VO(II), Pd(II) and Ag(I) complexes derived from 2-[(2-Hydroxy-naphthalen-1-ylmethylene)-amino]-benzoic acid were synthesized. The prepared imine ligands were analyzed by their melting point, IR, 1H NMR and 13C NMR spectroscopy. The investigated imine complexes were characterized by elemental analysis, FT IR, Uv-vis and thermal analysis (TGA) in air from ambient temperature ... Read more

Approach to Synthesis, Characterization, Antimicrobial Activities and Catalytic Activity of Some Transition Metal Complexes Containing Biologically Active Asymmetrical Tetradentate Ligands.
AIR AND MOISTURE STABLE COORDINATION COMPOUNDS OF FIRST TRANSITION METALS SUCH AS CO(II), NI(II) AND CU(II) WITH NEWLY DESIGNED SCHIFF BASE (BSIPH) INCORPORATING 5-BROMOSALICYALDEHYDE WITH ISATIN AND 4-NITRO-O-PHENYLENE DIAMINE HAVE BEEN SYNTHESIZED TO ELUCIDATE THE STRUCTURE OF METAL COMPLEXES. THEY ARE CHARACTERIZED BY ELEMENTAL ANALYSES, INFRARED, 1HNMR, 13CNMR, THERMAL ANALYSIS, UV-VISIBLE, CONDUCTIVITY AND MAGNETIC SUSCEPTIBILITY MEASUREMENTS. THE RESULTS SUGGEST THAT ... Read more

Complexation of Schiff bases incorporating of Salicylaldehyde Derivatives and Amino Acids to Copper(II) as an effective strategy for antimicrobial activity improvement, DNA Interaction and catalytic activity
Five Cu(II) complexes are tridentate Schiff bases amino acids ligands derived from condensation 3–methoxysalicylaldehyde (MS) or 4-diethylaminosalicylaldehyde (DS) with α-amino acids (L-phenylalanine(P), L-histidine (H), DL-tryptophane (T)). All ligands are analyzed by 1HNMR and 13CNMR. The investigated complexes have been prepared and characterized by elemental analysis, infrared spectra, ultraviolet-visible and thermal analysis in dynamic air atmosphere (40ml / min) at a ... Read more

2018-11-21 09:30:25 Keywords VO(II), Anti cancer, Antimicrobial, NMR, IR, TGA, Imine complexes,
Synthesis, Spectral Characterization, DNA Interaction, Antimicrobial  and Anticancer Activities  of Some Tri- and Tetra-dentate imine VO(II) Complexes
The new imine ligands were synthesized by the condensation reaction between 2-hydroxynaphthaldehyde or 3-ethoxysalicylaldehyde and _o_-phenylenediamine s in 1:1 molar ratio. The ligands react with vanadyl acetylacetonate in 1:1 molar ratio to give distorted and square pyramidal geometry for tri- and tetra-dentate imine complexes, respectively. All the complexes are non– hygroscopic in nature and stable to the atmosphere. The synthesized ... Read more

Synthesis, characterization, DNA cleavage and antimicrobial activity of Schiff base transition metal complexes containing heterocyclic ligand
SOME NOVEL SCHIFF BASE METAL COMPLEXES OF CU(II), CO(II), NI(II) AND FE(II) DERIVED FROM 2-AMINO-3-HYDROXYPYRIDINE AND 4-NITROBENZALDEHYDE WERE SYNTHESIZED. THESE COMPOUNDS WERE CHARACTERIZED BY ELEMENTAL ANALYSIS, MOLAR CONDUCTANCE, MAGNETIC SUSCEPTIBILITY, THERMAL MEASUREMENTS, INFRARED AND ULTRAVIOLET–VISIBLE SPECTRA. THE SCHIFF BASE AND METAL COMPLEXES DISPLAYED GOOD ACTIVITY (AGAINST THE BACTERIA, _ESCHERICHIA COLI,__SERRATIA MARCESCENCE_AND_MICROCCUS LUTEUS_, AND THE FUNGI _ASPERGILLUS FLAVUS_, _GETRICHM CANDIDUM _AND ... Read more

Some New Cr (III)  Mononuclear Complexes encompassing Tri- and Tetra-dentate Imine Ligands: Synthesis, Spectral Characterization and High Selectivity in Catalytic Oxidation of Benzyl alcohol
IN THE PRESENT CONTRIBUTION, SOME NOVEL CR (III) COMPLEXES WERE SYNTHESIZED FROM TRI- AND TETRA-DENTATE IMINE LIGANDS DERIVED FROM 3-ETHOXYSALICYLALDEHYDE OR 2-HYDROXYNAPHTHALDEHYDE WITH 2-AMINOPHENOL OR O-PHENYLENEDIAMINE. ALL THE PREPARED LIGANDS WERE AUTHENTICATED BY 1H, 13C NMR AND IR SPECTRA. INTERACTION OF THE SYNTHESIZED LIGANDS WITH CHROMIUM NITRATE PRODUCED THREE NOVEL CR(III) COMPLEXES. THE STRUCTURE OF THE PREPARED CR (III) COMPLEXES ... Read more

Synthesis, Characterization, DNA Binding Studies and Embryos toxicity of Some Novel  Iron(II)  Amino Acid  Schiff base  complexes
New Fe(II) Schiff base amino acid complexes derived from the condensation of o-hydroxynaphthaldehyde with L-alanine, L-phenylalanine, L-aspartic acid, L-histidine and L-arginine were synthesized and characterized by elemental analysis, IR, electronic spectra, and conductance measurements. The stoichiometry and the stability constants of the complexes were determined spectrophotometrically. The investigated Schiff bases exhibited tridentate coordination mode with the general formulae [Fe(HL)2]·nH2O. But ... Read more