Lobna Abdel-Mohsen Ebaid Nassr

Professor - Director of Quality Management Unit - Faculty of Science - Sohag University

Faculty of science

Address: Chemistry Department - Faculty of Science - Sohag University



Publications Which contain the keyword: Hydrophobic

2018-11-27 23:42:27 Keywords Hydrophobic, Surfactant, alkali halide,
Kinetic screening for the acid-catalyzed hydrolysis of some hydrophobic Fe(II) Schiff base amino acid chelates and reactivity trends in the presence of alkali halide and surfactant
Kinetics of acid-catalyzed hydrolysis of some high-spin Fe(II) Schiff base amino acid complexes were followed spectrophotometrically at 298 K under pseudo–first-order conditions. The studied ligands were derived from the condensation of 5-bromosalicylaldehyde with different four amino acids (phenylalanine, aspartic acid, histidine, and arginine). The acid hydrolysis reaction was studied in aqueous media and in the presence of different concentrations of ... Read more

Hydrophobicity, reactivity trends of base catalyzed hydrolysis of some novel high spin Fe(II) chelates in some binary aqueous solvent mixtures: Initial-transition state analysis
Rate constants for the base hydrolysis of bis(naphthylidene alanate)iron (II) (nali), bis(naphthylidene phenylalanate)iron(II) (nphali), bis(naphthylidene aspartate)iron(II) (nasi), (naphthylidene histidinate)iron(II) (nhi), bis(naphthylidene arginate)iron(II) (nari) have been reported in different binary aqueous solvent mixtures at 298 K. The observed reactivity trends are discussed in terms of the hydrophilic and hydrophobic forms of the complexes investigated, as well as the transfer chemical potentials ... Read more

Kinetic study of the base-catalyzed hydrolysis of novel high-spin hydrophobic Fe(II)-azomethine amino acid chelates: Salt and structure effects on the reactivity
The effect of salts on reactivity of basic hydrolysis of Fe(II) chelates bis(naphthylidenealanate) (nali), bis(naphthylidenephenylalanate) (nphali), bis(naphthylideneaspartate) (nasi), (naphthylidene histidinate) (nhi), bis(naphthylidene arginate) (nari) has been studied in aqueous media containing alkali metal halides, LiBr, NaCl, KBr, tetramethylammonium bromide (TMAB), tetraethylammonium bromide (TEAB), and tetrabutylammonium bromide (TBAB). The suggested mechanism of the base hydrolysis involves the parallel attack of OH−ions ... Read more