khalaf.ali

Khalaf Ali Fayez Abuamra

استاذ - أستاذ متفرغ

كلية العلوم

العنوان: قسم النبات والميكروبيولوجى -كلية العلوم -جامعة سوهاج

2

إعجاب

المنشورات و المؤلفات التي تحتوي علي الكلمة المفتاحية: IR


Some New  Ag(I),  VO(II)  and Pd(II) Chelates encompassing Tri-dentate Imine Ligand: Design, synthesis, Structure elucidation and DFT calculations for DNA Interaction, Antimicrobial, Anticancer Activities and Molecular Docking Studies
Some new complexes derived from VO(II), Ag(I) and Pd(II) metal ions and HNA imine ligand (L) _i.e. _(2-[(6-Allylidene-2-hydroxy-cyclohexa-1,3-dienylmethylene)-amino]-benzoic acid) have been prepared and their structures are elucidated _via_ molar conductance, elemental analyses, IR, NMR, magnetic susceptibility estimations and electronic spectral studies. Moreover, stability constants of the synthesized complexes were evaluated utilizing spectrophotometric technique. On the basis of molar conductance and ... إقراء المزيد

2018-10-10 11:53:46 الكلمات المفتاحية IR, imines, DNA binding, TGA, Chemo Sensor, VO(II), Pd (II), DFT, Conductivity,
Design,  Synthesis, Structure Inspection,  Biological Screening,  and DNA Binding Study of  Some New VO(II), Pd (II) and Ag(I)  Chelates incorporating Tri-dentate Chemo Sensor Imine Ligand
The present study was conducted to synthesis of some new imine VO(II), Pd(II) and Ag(I) complexes derived from 2-[(2-Hydroxy-naphthalen-1-ylmethylene)-amino]-benzoic acid were synthesized. The prepared imine ligands were analyzed by their melting point, IR, 1H NMR and 13C NMR spectroscopy. The investigated imine complexes were characterized by elemental analysis, FT IR, Uv-vis and thermal analysis (TGA) in air from ambient temperature ... إقراء المزيد

2018-10-10 14:22:18 الكلمات المفتاحية IR, nanoparticles, Schiff-Base Complexes, Nanosized Ni/Cu, Benzyl alcohol, Sonochemical, thermal analysis, benzaldehyde,
Catalytic Oxidation of Benzyl Alcohol using Nanosized Ni/Cu  Schiff-Base Complexes and their Metal Oxides Nanoparticles
Three novel nanosized Cu and Ni Schiff-base complexes (ahpvCu, ahpnbCu, and ahpvNi) incorporating imine ligands derived from the condensation of 2-amino-3-hydroxypyridine with either 3-methoxysalicylaldehyde or 4-nitrobenzaldehyde were synthesized by a sonochemical approach. The structure of the ligands and their complexes was confirmed by IR, NMR spectroscopy, electronic spectra, elemental analysis, TGA, molar conductivity, and magnetic moment analyses. The results revealed ... إقراء المزيد

2018-10-12 08:40:27 الكلمات المفتاحية Isotherm, Plant, Adsorption, Heavy metal, Biosorbent, Toxic, Removal, thermodynamic parameters, IR, Water purification, wastewater,
Adsorption of the heavy metal ions onto biosorbents: A review
Heavy metal pollution in result of human activities such as mining has become a critical environmental issue nowadays. Various methods for removing heavy metal from industrial wastewater have been investigated. This paper reviews an economic and environment friendly process known as biosorption. Biosorption is a potential alternative to the conventional treatment processes such as adsorption on activated carbon. Some factors ... إقراء المزيد

2018-10-05 11:42:34 الكلمات المفتاحية Antimicrobial activity, TGA, IR, DNA interaction, imidazoles, Ternary complexes, Glutamine, glutaric and glutamic acid,
Desighn, Characterization and Biological activity of new mixed ligand transition metal complexes of glutamine, glutaric and glutamic acid with nitrogen based ligands.
A new series of Cu(II), Co(II), Ni(II) and Fe(II) ternary complexes of glutamine, glutaric and glutamic acid with imidazole derivatives have been synthesized. The nature of bonding and the stereochemistry of the complexes have been deduced from elemental analyses, infrared, electronic spectra, conductivity measurements and thermogravimetric analysis. The structure of [Co(glu)(IMI)2] and [Fe(glu)(IMI)2(H2O)2] complexes was validated using quantum mechanics calculations ... إقراء المزيد

2018-10-05 12:01:10 الكلمات المفتاحية IR, TGA, Conductivity, amino acid, novel copper(II), DNA interaction, characterization, Bromosalicylaldehyde,
Design, Characterization, DNA Interaction and antimicrobial of novel copper(II) Schiff base amino acid complexes
Five novel copper(II) complexes derived from the condensation between 5-bromosalicyaldhyde (bs) and α-amino acids (L-alanine, L-phenylalanine, L-aspartic acid, L-histidine and L-arginine) were synthesized and characterized by their elemental analyses, thermogravemetric analysis, IR, electronic spectra and conductance and magnetic measurements. Moreover, the stoichiometry and the stability constants of the prepared complexes have been determined spectrophotometrically. The Results indicated that the Schiff ... إقراء المزيد

2018-10-05 12:14:37 الكلمات المفتاحية amino acid, Nano Sized, Cu(II) complexes, DNA interaction, Salicylaldehyde Derivatives, TEM, IR, TGA, Conductivity,
Nano sized ternary Cu(II) complexes Encompassing Salicylaldehyde Derivatives and Amino Acids as an Effective Strategy for Antimicrobial Activity Improvement and DNA Interaction
A series of ternary Cu(II) complexes encompassing ONO donor Schiff base amino acid ligands were synthesized from condensation of 3–methoxysalicylaldehyde (MS) or 4-diethylamino salicylaldehyde (DS) with α-amino acids (L-phenylalanine (Phe), L-histidine (His), DL-tryptophan (Trp)) as primary ligand and 2, 4-bipridyl (DP) as secondary ligand. All the prepared compounds were characterized by melting points, decomposition temperatures, elemental analysis, UV-Vis, IR spectra, ... إقراء المزيد

2018-10-06 08:41:37 الكلمات المفتاحية superparamagnetic materials, VSM, TEM, Robust Synthesis, Magnetite Nanoparticles, Functionalization, SEM, IR,
A Robust Synthesis of Magnetite Nanoparticles of Desired Size and the Functionalization Thereof
The synthesis of magnetite nanoparticles is an area of permanent interest in view of their high technological applications including Biomedicine and Biosensing. These nanoparticles are used as enhanced magnetic resonance imaging (MRI) agents, for biological separation and magnetic drug delivery systems, and magnetic hyperthermia treatment [1]. Magnetite nanoparticles of about 20 nm in diameter and low polydispersity were prepared heating ... إقراء المزيد

2018-10-01 09:29:12 الكلمات المفتاحية HCV genotype 4, Steatosis, VAI, TyG, IR,
Insulin Resistance, Visceral Adiposity Index and TyG Index in Genotype-4 Chronic HCV Patients and Their Relation to Hepatic Histopathology
INTRODUCTION: Hepatitis C virus (HCV) genotype 4 is the most prevalent in Egypt. Vis-ceral adiposity index (VAI) and (TyG) index are newly developed indices for assess-ment of metabolic syndrome (MS) and insulin resistance (IR). We aimed at comparing their levels in HCV-patients with healthy controls and validate their use for prediction of hepatic histopathological changes. PATIENT AND METHODS: 78 chronic ... إقراء المزيد

2018-10-03 10:12:16 الكلمات المفتاحية TEM, SEM, IR, XRD, Delonix regia, lamboyant Pod, Nano Sized, Disposal, Cd(II) ions, Adsorption, Toxic,
Disposal of Heavy Transition Cd(II) ions from Aqueous Solution utilizing Nano Sized Flamboyant Pod (Delonix regia)
The absorption of toxic heavy metal by natural adsorbents from water were indicated by investigation the effect of nano sized (_Delonix regia _(DR)) and (CADR) citric acid_ Delonix regia_ chemically modified adsorbent for removing the Cd2+ ions. Different techniques were employed for characterizing the adsorbent (_Delonix regia_) such energy dispersive analysis of X-ray (EDAX), Fourier transform infrared spectroscopy (FT-IR), Transmission ... إقراء المزيد