ahmedabudief

Dr. Ahmed Mohammed Abu-Dief Mohammed

Assistant Professor - Assistant professor of Inorganic and Physical Chemistry

Faculty of science

Address: Behind hospital of Sohag University - Ali Ebn Abi Taleb Street

128

Like

Publications Which contain the keyword: laser dyes


2018-11-28 16:53:16 Keywords chromen-2-one, laser dyes, hydroxide ion attack, Kinetics,
Kinetic study and reactivity trends of hydroxide ion attack on some chromen-2-one laser dyes in binary water–methanol and water–acetone mixtures
We have investigated the kinetics of hydroxide ion attack at iron(II) chelates with 5-bromosalicylidene derivatives of amino acids (alanine, phenylalanine, aspartic acid, histidine, and arginine) in binary aqueous mixed solvents at 298 K. The observed reactivity trends are discussed in connection with the complexes hydrophobicity/hydrophilicity, transfer chemical potentials of hydroxide ion and the complex, and the solvent effects. Read more

2018-10-05 11:38:58 Keywords solvent effect, base hydrolysis, Chromen-2-ones, laser dyes,
Solvent and Temperature effects on Reactivity trends of Base-catalyzed hydrolysis of some Chromen-2-one laser dyes
In the present study, reactivity base-catalyzed hydrolysis of 7-dimethylamino-4-methyl-2H-chromen-2-one (DMAC) and 7-diethylamino-4-methyl-2H-chromen-2-one (DEAC) in binary aqueous-methanol and aqueous-acetone mixtures was examined at 298 K. Kinetic results, rate laws and reaction mechanisms were established. Moreover, the change in the activation energy barrier of the investigated compounds from water to water–methanol and water–acetone mixtures was estimated from the kinetic data. Base-catalyzed hydrolysis ... Read more