The new imine ligands were synthesized by the condensation reaction between 2-hydroxynaphthaldehyde or 3-ethoxysalicylaldehyde and _o_-phenylenediamine s in 1:1 molar ratio. The ligands react with vanadyl acetylacetonate in 1:1 molar ratio to give distorted and square pyramidal geometry for tri- and tetra-dentate imine complexes, respectively. All the complexes are non– hygroscopic in nature and stable to the atmosphere. The synthesized ...
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