Reactivity tracers of the hydrolysis of Fe(II)-bis(salicylidene) complexes: Initial -transition states analysis and enhanced impact of tensides on the kinetic trends
The kinetics of the acid hydrolysis reaction of Fe(II)-bis(salicylidene) complexes were followed under pseudo–first-order conditions ([H+] >> [complex]) at 298 K. The ligands of the studied azomethine complexes were derived from the condensation of salicylaldehyde with different five α-amino acids. The hydrolysis reactions were studied in acidic medium at different ratios (v/v) of aqua–organic mixtures. The decrease in the dielectric ... Read more