Kinetic and mechanistic aspects of reactivity of the oxidation of some Fe(II)–tris Schiff base complexes by peroxydisulfate: Spectrophotometric tracer and solvent effect on the reactivity
The kinetics of the oxidation of some Fe(II)–Tris Schiff base complexes by peroxydisulfate was studied spectrophotometrically in the aqueous medium and in the organic– aqua binary mixture. The inspected complexes were derived from the condensation of 2- acetylpyridine and substituted benzylamines. The oxidation reaction of the studied complexes was followed at 303 K under pseudo–first-order conditions. It was found that ... إقراء المزيد