lobna.nassr

Lobna Abdel-Mohsen Ebaid Nassr

Professor - Head Of Chemistry Department- Director of Quality Management Unit - Faculty of Science - Sohag University

Faculty of science

Address: Chemistry Department - Faculty of Science - Sohag University

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Publications Which contain the keyword: Base-catalyzed hydrolysis

Reactivity trends and kinetic inspection of hydroxide ion attack and DNA interaction on some pharmacologically active agents of Fe(II) amino acid Schiff base complexes at different temperatures

2018-11-28 20:59:46 Keywords DNA interaction, Base-catalyzed hydrolysis, Fe(II),
Reactivity trends and kinetic inspection of hydroxide ion attack and DNA interaction on some pharmacologically active agents of Fe(II) amino acid Schiff base complexes at different temperatures
The reactivity of few novel high-spin Fe(II) complexes of Schiff base ligands derived from 2-hydroxynaphthaldehyde and some variety of amino acids with the OH− ion has been examined in an aqueous mixture at the temperature range from 10 to 40°C. Based on the kinetic investigations, the rate law and a plausible mechanism were proposed and discussed. The general rate equation ... Read more

Hydrophobicity and kinetic inspection of hydroxide ion attack on some chromen-2-one laser dyes in binary aqueous–methanol and aqueous–acetone mixtures: Initial state-transition state analysis

2018-09-16 13:35:40 Keywords Initial-transition state, Base-catalyzed hydrolysis, reaction mechanism, solvent effect, Chromen-2-ones,
Hydrophobicity and kinetic inspection of hydroxide ion attack on some chromen-2-one laser dyes in binary aqueous–methanol and aqueous–acetone mixtures: Initial state-transition state analysis
In the present study, reactivity base-catalyzed hydrolysis of 7-dimethylamino-4-methyl-2H-chromen-2-one (DMAC) and 7-diethylamino-4-methyl-2H-chromen-2-one (DEAC) in binary aqueous–methanol and aqueous–acetone mixtures was examined at 298 K. Kinetic results, rate laws and reaction mechanisms were established. Moreover, the change in the activation energy barrier of the investigated compounds from water to water–methanol and water–acetone mixtures was estimated from the kinetic data. Base-catalyzed hydrolysis ... Read more

Initial State and Transition State Contributions to Reactivity Trends of Base-Catalyzed Hydrolysis of Some Nitro Chromen-2-One Derivatives

2018-09-16 15:02:56 Keywords Initial state, Transfer chemical potential, Activation energy barrier, Base-catalyzed hydrolysis, Chromene-2-Ones,
Initial State and Transition State Contributions to Reactivity Trends of Base-Catalyzed Hydrolysis of Some Nitro Chromen-2-One Derivatives
Base-catalyzed hydrolysis of 6-nitro-2H-chromen-2-one (NC) and 6-nitro-2H-chromen-2-one-3-carboxylic acid (NCC) in binary water/methanol and water/acetone mixtures were studied kinetically at 298 K. The changes in the activation barrier of the investigated compounds from water to water/methanol and water/acetone mixtures were estimated from the kinetic data. Solvent effects on the reactivity trends were analyzed into initial state and transition state components. These ... Read more

Kinetics, reactivity, initial-transition state analysis and thermodynamic parameters of base-catalyzed hydrolysis of coumalic acid in solvents with different polarities

2018-09-11 12:45:20 Keywords Isokinetic temperature, Transition state, Initial state, Transfer chemical potential, Activation energy barrier, Base-catalyzed hydrolysis, Coumalic acid, Kinetics, aqueous-methanol, aqueous-acetone,
Kinetics, reactivity, initial-transition state analysis and thermodynamic parameters of base-catalyzed hydrolysis of coumalic acid in solvents with different polarities
Base-catalyzed hydrolysis of coumalic acid (COU) in binary aqueous-methanol and aqueous-acetone mixtures has been studied kinetically at a temperature range from 283 to 313 K. Moreover, the change in the activation energy barrier of COU from water to water–methanol and water–acetone mixtures is estimated from the kinetic data. Solvent effects on reactivity trends have been analyzed into initial and transition ... Read more

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