hazem95

أ. د/ حازم محمود المشنب

استاذ - عميد كلية العلوم بسوهاج

كلية العلوم

العنوان: جامعة سوهاج - كلية العلوم - قسم الفيزياء

24

إعجاب

المنشورات و المؤلفات التي تحتوي علي الكلمة المفتاحية: Hydrophobic


2018-11-27 23:42:27 الكلمات المفتاحية Hydrophobic, Surfactant, alkali halide,
Kinetic screening for the acid-catalyzed hydrolysis of some hydrophobic Fe(II) Schiff base amino acid chelates and reactivity trends in the presence of alkali halide and surfactant
Kinetics of acid-catalyzed hydrolysis of some high-spin Fe(II) Schiff base amino acid complexes were followed spectrophotometrically at 298 K under pseudo–first-order conditions. The studied ligands were derived from the condensation of 5-bromosalicylaldehyde with different four amino acids (phenylalanine, aspartic acid, histidine, and arginine). The acid hydrolysis reaction was studied in aqueous media and in the presence of different concentrations of ... إقراء المزيد

2018-09-11 12:55:55 الكلمات المفتاحية Solvent, Hydrophobic, Hydrophilic, Kinetics, Hydration, Solvolysis, Reactivity, Initial state-transition state,
Hydrophobicity, reactivity trends of base catalyzed hydrolysis of some novel high spin Fe(II) chelates in some binary aqueous solvent mixtures: Initial-transition state analysis
Rate constants for the base hydrolysis of bis(naphthylidene alanate)iron (II) (nali), bis(naphthylidene phenylalanate)iron(II) (nphali), bis(naphthylidene aspartate)iron(II) (nasi), (naphthylidene histidinate)iron(II) (nhi), bis(naphthylidene arginate)iron(II) (nari) have been reported in different binary aqueous solvent mixtures at 298 K. The observed reactivity trends are discussed in terms of the hydrophilic and hydrophobic forms of the complexes investigated, as well as the transfer chemical potentials ... إقراء المزيد

2018-09-11 16:51:41 الكلمات المفتاحية salt effects, Hydrophobic, Hydrophilic, Kinetics, Reactivity, reaction mechanism, base hydrolysis, aqueous solution,
Kinetic study of the base-catalyzed hydrolysis of novel high-spin hydrophobic Fe(II)-azomethine amino acid chelates: Salt and structure effects on the reactivity
The effect of salts on reactivity of basic hydrolysis of Fe(II) chelates bis(naphthylidenealanate) (nali), bis(naphthylidenephenylalanate) (nphali), bis(naphthylideneaspartate) (nasi), (naphthylidene histidinate) (nhi), bis(naphthylidene arginate) (nari) has been studied in aqueous media containing alkali metal halides, LiBr, NaCl, KBr, tetramethylammonium bromide (TMAB), tetraethylammonium bromide (TEAB), and tetrabutylammonium bromide (TBAB). The suggested mechanism of the base hydrolysis involves the parallel attack of OH−ions ... إقراء المزيد

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