tarek_ali

Tarek T. Ali

Professor - Professor

Faculty of science

Address: Chemistry Department, Faculty of Science, Sohag University, Sohag, P.O.Box 82524, Egypt

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Publications Which contain the keyword: Chromen-2-ones

Solvent and Temperature effects on Reactivity trends of Base-catalyzed hydrolysis of some Chromen-2-one laser dyes

2018-10-05 11:38:58 Keywords solvent effect, base hydrolysis, Chromen-2-ones, laser dyes,
Solvent and Temperature effects on Reactivity trends of Base-catalyzed hydrolysis of some Chromen-2-one laser dyes
In the present study, reactivity base-catalyzed hydrolysis of 7-dimethylamino-4-methyl-2H-chromen-2-one (DMAC) and 7-diethylamino-4-methyl-2H-chromen-2-one (DEAC) in binary aqueous-methanol and aqueous-acetone mixtures was examined at 298 K. Kinetic results, rate laws and reaction mechanisms were established. Moreover, the change in the activation energy barrier of the investigated compounds from water to water–methanol and water–acetone mixtures was estimated from the kinetic data. Base-catalyzed hydrolysis ... Read more

Solvent effects on the kinetics and reactivity trends of base-catalyzed hydrolysis of some chromen-2-one indicator dyes at different temperatures

2018-10-03 05:56:34 Keywords base hydrolysis, Kinetic parameters, solvent effect, Chromen-2-ones, Dyes,
Solvent effects on the kinetics and reactivity trends of base-catalyzed hydrolysis of some chromen-2-one indicator dyes at different temperatures
Base hydrolysis of 7-hydroxy coumarin (HC) and 7-hydroxy-coumarin-4-acetic acid (HCA) in aqueous-methanol and aqueous-acetone mixtures were studied kinetically at temperature range from 283 to 313 K. The activation parameters of the reactions were evaluated and discussed. Moreover, the change in the activation energy barrier of the investigated compounds from water to water-methanol and water-acetone mixtures was estimated from the kinetic ... Read more

Hydrophobicity and kinetic inspection of hydroxide ion attack on some chromen-2-one laser dyes in binary aqueous–methanol and aqueous–acetone mixtures: Initial state-transition state analysis

2018-09-16 13:35:40 Keywords Initial-transition state, Base-catalyzed hydrolysis, reaction mechanism, solvent effect, Chromen-2-ones,
Hydrophobicity and kinetic inspection of hydroxide ion attack on some chromen-2-one laser dyes in binary aqueous–methanol and aqueous–acetone mixtures: Initial state-transition state analysis
In the present study, reactivity base-catalyzed hydrolysis of 7-dimethylamino-4-methyl-2H-chromen-2-one (DMAC) and 7-diethylamino-4-methyl-2H-chromen-2-one (DEAC) in binary aqueous–methanol and aqueous–acetone mixtures was examined at 298 K. Kinetic results, rate laws and reaction mechanisms were established. Moreover, the change in the activation energy barrier of the investigated compounds from water to water–methanol and water–acetone mixtures was estimated from the kinetic data. Base-catalyzed hydrolysis ... Read more

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