lobna.nassr

Lobna Abdel-Mohsen Ebaid Nassr

Professor - Head Of Chemistry Department- Director of Quality Management Unit - Faculty of Science - Sohag University

Faculty of science

Address: Chemistry Department - Faculty of Science - Sohag University

53

Like
9 58 19 49 5 36 2K 1.3K
220

Newly Added
  • Courses 9
  • Course Supplements 58
  • Courses Tasks 19
  • Publications 49
  • Office hours 5
  • Announcements 36
  • File uploaded 56
  • Downloaded Times 161

Publications Which contain the keyword: Schiff base

Novel mechanistic aspects on the reaction between low spin Fe(II) Schiff base amino acid complexes and hydrogen peroxide—Spectrophotometric tracer of intraperoxo intermediate catalyzed reaction

2019-01-24 12:28:42 Keywords Hydrogen peroxide, Amino acids, Schiff base,
Novel mechanistic aspects on the reaction between low spin Fe(II) Schiff base amino acid complexes and hydrogen peroxide—Spectrophotometric tracer of intraperoxo intermediate catalyzed reaction
The kinetics and mechanism of the reaction of hydrogen peroxide with some Fe(II) Schiff base complexes were investigated spectrophotometrically in aqueous solution at pH 8 and 35 °C under pseudo-first-order conditions. The used ligands were derived from salicylaldehyde or _o_-hydroxynaphthaldehyde and some amino acids (l-leucine, l-iso-leucine, l-serine, l-methionine and dl-tryptophan). It was found that the formation of the purple interaperoxo ... Read more

New palladium (II) and silver (I) Schiff base complexes Promising antibiotic and anticancer agents

2018-11-26 08:20:45 Keywords DNA interaction, Antimicrobial activity, anticancer activity, complexes, Schiff base, VO(II), Pd (II),
New palladium (II) and silver (I) Schiff base complexes Promising antibiotic and anticancer agents
Some new complexes derived from Ag (I) and Pd(II) metal ions and HNA imine ligand (L) _i.e. _(2-[(6-Allylidene-2-hydroxy-cyclohexa-1,3-dienylmethylene)-amino]-benzoic acid) have been synthesized and characterized by elemental analyses, molar conductance, magnetic susceptibility measurements, IR, NMR and electronic spectral studies. Moreover, the stability constants of the synthesized complexes were determined spectrophotometrically. On the basis of molar conductance and elemental analyses the complexes ... Read more

Synthesis, characterization, DNA cleavage and antimicrobial activity of Schiff base transition metal complexes containing heterocyclic ligand

2018-11-21 09:20:56 Keywords DNA interaction, Schiff base, Transition Metal Complexes, IR, TGA, NMR, Antimicrobial activity, Electronic spectra,
Synthesis, characterization, DNA cleavage and antimicrobial activity of Schiff base transition metal complexes containing heterocyclic ligand
SOME NOVEL SCHIFF BASE METAL COMPLEXES OF CU(II), CO(II), NI(II) AND FE(II) DERIVED FROM 2-AMINO-3-HYDROXYPYRIDINE AND 4-NITROBENZALDEHYDE WERE SYNTHESIZED. THESE COMPOUNDS WERE CHARACTERIZED BY ELEMENTAL ANALYSIS, MOLAR CONDUCTANCE, MAGNETIC SUSCEPTIBILITY, THERMAL MEASUREMENTS, INFRARED AND ULTRAVIOLET–VISIBLE SPECTRA. THE SCHIFF BASE AND METAL COMPLEXES DISPLAYED GOOD ACTIVITY (AGAINST THE BACTERIA, _ESCHERICHIA COLI,__SERRATIA MARCESCENCE_AND_MICROCCUS LUTEUS_, AND THE FUNGI _ASPERGILLUS FLAVUS_, _GETRICHM CANDIDUM _AND ... Read more

Kinetics of acid hydrolysis and reactivity of some antibacterial hydrophilic iron (II) imino-complexes

2018-09-27 05:21:06 Keywords Schiff base,
Kinetics of acid hydrolysis and reactivity of some antibacterial hydrophilic iron (II) imino-complexes
Kinetic study of acid hydrolysis of some hydrophilic Fe(II) Schiff base amino acid complexes with antibacterial properties was performed using spectrophotometry. The Schiff base ligands were derived from sodium 2-hydroxybenzaldehyde-5-sulfonate and glycine, L-alanine, L-leucine, L-isoleucine, DL-methionine, DL-serine, or L-phenylalanine. The reaction was studied in aqueous media under conditions of pseudo-first order kinetics. Moreover, the acid hydrolysis was studied at different ... Read more

A review on versatile applications of transition metal complexes incorporating Schiff bases

2018-09-27 05:23:13 Keywords Schiff base,
A review on versatile applications of transition metal complexes incorporating Schiff bases
Schiff bases and their complexes are versatile compounds synthesized from the condensation of an amino compound with carbonyl compounds and widely used for industrial purposes and also exhibit a broad range of biological activities including antifungal, antibacterial, antimalarial, antiproliferative, anti-inflammatory, antiviral, and antipyretic properties. Many Schiff base complexes show excellent catalytic activity in various reactions and in the presence of ... Read more

Novel sandwich triple-decker dinuclear NdIII-(bis-N,N′-p-bromo-salicylideneamine-1,2-diaminobenzene) complex

2018-09-16 14:28:13 Keywords single-crystal X-ray study, Lanthanide complex, Schiff base, Luminescence, Magnetism,
Novel sandwich triple-decker dinuclear NdIII-(bis-N,N′-p-bromo-salicylideneamine-1,2-diaminobenzene) complex
In the search of new multifunctional molecular materials, the present paper introduces the work performed with the Salen-type Schiff base: bis-_N_,_N_′-_p_-bromo-salicylideneamine-1,2-diaminobenzene (H2bsph), to attain novel coordination complexes containing lanthanides centers (LnIII). So far, our studies have shown that the combination in acetone of the well-known H2bsph ligand, a base and NdIII(NO3)3·6H2O, results in a yellow solid which crystalline forms has ... Read more

Design, characterization, teratogenicity testing, antibacterial, antifungal and DNA interaction of few high spin Fe(II) Schiff base amino acid complexes

2018-09-16 14:32:30 Keywords Schiff base, amino acid, Fe(II), Teratogenicity, DNA interaction, antibacterial, Antifungal, high spin, Design, IR,
Design, characterization, teratogenicity testing, antibacterial, antifungal and DNA interaction of few high spin Fe(II) Schiff base amino acid complexes
In this study, new Fe(II) Schiff base amino acid chelates derived from the condensation of o-hydroxynaphthaldehyde with l-alanine, l-phenylalanine, l-aspartic acid, l-histidine and l-arginine were synthesized and characterized via elemental, thermogravimetric analysis, molar conductance, IR, electronic, mass spectra and magnetic moment measurements. The stoichiometry and the stability constants of the complexes were determined spectrophotometrically. Correlation of all spectroscopic data suggested ... Read more

Synthesis, physicochemical studies, embryos toxicity and DNA interaction of some new Iron(II) Schiff base amino acid complexes

2018-09-16 14:36:08 Keywords Fe(II) complexes, Toxicity, DNA interaction, amino acid, Schiff base,
Synthesis, physicochemical studies, embryos toxicity and DNA interaction of some new Iron(II) Schiff base amino acid complexes
New Fe(II) Schiff base amino acid complexes derived from the condensation of o-hydroxynaphthaldehyde with l-alanine, l-phenylalanine, l-aspartic acid, l-histidine and l-arginine were synthesized and characterized by elemental analysis, IR, electronic spectra, and conductance measurements. The stoichiometry and the stability constants of the complexes were determined spectrophotometrically. The investigated Schiff bases exhibited tridentate coordination mode with the general formulae [Fe(HL)2]·nH2O for ... Read more

Tailoring, physicochemical characterization, antibacterial and DNA binding mode studies of Cu(II) Schiff bases amino acid bioactive agents incorporating 5-bromo-2-hydroxybenzaldehyde

2018-09-11 16:22:26 Keywords Intercalation, Calf thymus DNA, Cu(II) chelates, Schiff base, Amino acids,
Tailoring, physicochemical characterization, antibacterial and DNA binding mode studies of Cu(II) Schiff bases amino acid bioactive agents incorporating 5-bromo-2-hydroxybenzaldehyde
Five novel Cu(II) complexes derived from the condensation between 5-bromosalicylaldehyde (bs) and α-amino acids (L-alanine, l-phenylalanine, L-aspartic acid, L-histidine and L-arginine) were synthesized and characterized by their elemental analyses, thermogravimetric analysis, IR, mass and electronic spectra, conductance and magnetic measurements. Moreover, the stoichiometry and the stability constants of the prepared complexes have been determined spectrophotometrically using continuous variation and molar ... Read more

A review on versatile applications of transition metal complexes incorporating Schiff bases

2018-09-11 16:36:51 Keywords Complex, Schiff base, Bio-inorganic chemistry, Catalysis, Antimicrobial, Dyes, Polymers,
A review on versatile applications of transition metal complexes incorporating Schiff bases
Schiff bases and their complexes are versatile compounds synthesized from the condensation of an amino compound with carbonyl compounds and widely used for industrial purposes and also exhibit a broad range of biological activities including antifungal, antibacterial, antimalarial, antiproliferative, anti-inflammatory, antiviral, and antipyretic properties. Many Schiff base complexes show excellent catalytic activity in various reactions and in the presence of ... Read more