The improvements in understanding lead/acid batteries have been started within the last fifteen years. The technologies and designs of the battery will incorporate more and thinner plates with grids produced from continuous processes using stronger, more corrosion-resistant grid alloys and having longer life at elevated temperature. Battery grids will become having higher utilization of active material and producing more uniform discharges [Prengaman, 1999; Burashnikova et al., 2012; Burashnikova et al., 2013; Gao et al., 2014]. It is well known that, the alloying content plays an important role in the improvement of the battery grids properties. In this study, addition of alloying elements to Pb has been studied for a wide range of alloy compositions. The mechanical properties of alloy was improved with adding 0.03% calcium. Barium introduction into lead-tin-calcium alloys increases their hardness, reduces their electrochemical activity, and improves their corrosion stability [Burashnikova et al., 2013]. More complicated role on kinetics of the formation, passivation and growth rates of PbO and PbO2 films was obtained, [Osorio et al., 2009; Prengaman et al., 1984; Prengaman, 2006; Lakshmi et al., 1998] as reported by Rocca and Steinmetz, [Rocca, and Steinmetz, 1984] Pb-Sn, Pb-Sb, Pb-Ca-Sn and Pb- Ca-Sn-Sb alloys have been applied in the production of negative grids, connectors, post and strap components of both VRLA and SLI batteries,
[Osorio et al., 2010; Achtermann and Greenlee, 1991; Wirtz, 1996; Prengaman, 2001]. The stability of battery grid dimensions depends on the mechanical stresses of the charge/discharge reactions with bending and stretching or wrapping. The literature survey showed that, new additives have been incorporated in the grid alloy composition in order to improve its performance. [Prengaman, 2001; Al-Ganainy et al., 2004; Rezaei and Damiri, 2005; Furukawa and Nehyo, 2004; Guo et al., 2009; Liu et al., 2001; Zhou et al., 2004; Shiota et al., 2005; Hirasawa et al., 2000; Stein et al., 2004; Zhang et al., 2012]. Accordingly, rare earth elements, Ag and Te were added with the purpose of enhancing the corrosion resistance.