Quality of water is a pre-requisite for the success of an irrigation project. With this view, an effort was made to assess the groundwater quality of a kheragarah tehsil of Agra, U.P., India. Based on IRS-P6 LISS III satellite image of dry season (May, 2009), representative pedons were chosen and for each groundwater samples were collected. Both groundwater and soil samples were analyzed for chemical properties. Further, the Sodium Adsorption Ratio (SAR), Adjusted Sodium Adsorption Ratio (Adj. SAR) and Residual Sodium Carbonates (RSC) were computed. This revealed that most of groundwater samples were not suitable for irrigation and cure should be taken to reduce the hazards and to improve the soil productivity.