Kinetic screening for the acid-catalyzed hydrolysis of some hydrophobic Fe(II) Schiff base amino acid chelates and reactivity trends in the presence of alkali halide and surfactant
Kinetics of acid-catalyzed hydrolysis of some high-spin Fe(II) Schiff base amino acid complexes were followed spectrophotometrically at 298 K under pseudo–first-order conditions. The studied ligands were derived from the condensation of 5-bromosalicylaldehyde with different four amino acids (phenylalanine, aspartic acid, histidine, and arginine). The acid hydrolysis reaction was studied in aqueous media and in the presence of different concentrations of ... Read more