ahmedabudief

Dr. Ahmed Mohammed Abu-Dief Mohammed

Assistant Professor - Assistant professor of Inorganic and Physical Chemistry

Faculty of science

Address: Behind hospital of Sohag University - Ali Ebn Abi Taleb Street

117

Like
Synthesis, catalysis, antimicrobial activity and DNA interactions of new Cu(II)-Schiff base complexes
Structural features and catalytic activities of five ternary copper (II)-Schiff base complexes are investigated. The ligands are derived from 3–methoxysalicylaldehyde (MS) or 4– diethylaminosalicylaldehyde (DS) and amino acids {L-phenylalanine (Phe), L histidine (His) or DL-tryptophan (Trp)}, as primary ligands, and 2,4’-bipyridyl (DP) as secondary ligand. Cu(II)- complexes are characterized by various physicochemical tools. The catalytic efficiency of Cu(II)-complexes is studied ... Read more

Facile Synthesis and Characterization of Novel Gd2O3/CdO Binary Mixed Oxide Nanocomposites
In this study, pure cadmium oxide (CdO) nanoparticles as well as a mixed gadolinium oxide (Gd2O3)/CdO nanocomposites with mixing contents (0% ≤ Gd2O3 content ≤ 15%) were synthesized via facile precipitation technique followed by calcined treatment. The synthesized nano-powders were characterized by various techniques in terms of their structure, morphology, composition, and optical properties. X-ray diffraction analysis illustrated that all ... Read more

Design, Synthesis and Structural Inspection of Some Novel Di- And Tri-Azomethene Compounds as Chemo Sensors for the Detection of Various Metal Ions
In this study, NBA imine compound was synthesized via an easy one-pot condensation of 3-nitro-benzaldyhide with 2-amino benzoic acid in 1:1 ratio and DAPH imine compound derived from 2,6-diacetyl pyridine and phenyl hydrazine hydrochloride. Consequences of the newly synthesized compounds hooked up with the aid of FT-IR, elemental analyses, 13C-NMR ,1H-NMR and digital spectral research. Experiments had been consistent with ... Read more

The synthesis of CuO and NiO nanoparticles by facile thermal decomposition of metal-Schiff base complexes and an examination of their electric, thermoelectric and magnetic Properties
In this study, CuO and NiO NPs have been synthesized by facile thermal decomposition of Schiff base complexes and their physical properties have been examined. The synthesized CuO and NiO NPs are crystallized in polycrystalline monoclinic and cubic structures with average particle size 17 ± 0.4 and 62 ± 1 nm, respectively. The electrical conductivity measurements confirm that the conduction ... Read more

Electric, Thermoelectric and Magnetic Properties of Nickel(II) Imine Nanocomplexes
Production of novel organic semiconductor nanomaterials is essential for enabling the development of personal, portable and flexible electronic modules. This work presents Ni(II)-Schiff base complexes with enhanced Seebeck coefficient and weak ferromagnetic ordering for thermoelectric and magnetic devices. Four Ni(II)-Schiff base complexes (namely [Ni(C12">1212H10">1010N3O4Br)]⋅">⋅⋅2H2O, [Ni(C16">1616H11">1111N3O4)">4)4)]⋅">⋅⋅2H2O, [Ni(C21">2121H14">1414N5O8Br)] and [Ni(C25">2525H17">1717N5O8)">8)8)]⋅1/2">⋅1/2⋅1/2H2O) have been synthesized in nanosized dimensions. The electrical and thermoelectric properties have ... Read more

The electric and thermoelectric properties of Cu(II)-Schiff base nano-complexes
have been widely investigated. However, their thermoelectric (TE) properties remain unreported. This work presents Cu(II)-Schiff base complexes as promising materials for TE power generation. Therefore, three Cu(II)-Schiff base complexes (namely, [Cu(C32H22N4O2)].3 2H2O, [Cu(C23H17N4O7Br)], and [Cu(C27H22N4O8)].H2O) have been synthesized in nanosized scale. The electric and TE properties have been studied and comprehensive discussions have been presented to promote the nano-complexes (NCs) ... Read more

Synthesis, characterization and photocatalysis enhancement of Eu2O3-ZnO mixed oxide nanoparticles
Pure ZnO nanoparticles (NPs) and mixed Eu2O3 and ZnO NPs with different Eu2O3 ratios (5%, 10%, and 15%) were synthesized by a precipitation method under optimum conditions. The synthesized samples were characterized by means of X-ray diffraction, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy, transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, and UV–vis diffuse reflectance spectroscopy. ... Read more

Functionalization of Magnetic Nanoparticles for Drug Delivery
Magnetic nanoparticles (MNPs) possess unique magnetic properties and the ability to function at the cellular and molecular level of biological interactions making them an attractive platform as carriers for drug delivery. Recent advances in nanotechnology have improved the ability to specifically tailor the features and properties of MNPs for these biomedical applications. To better address specific clinical needs, MNPs with ... Read more

Electric, thermoelectric and magnetic characterization of γ-Fe2O3 and Co3O4 nanoparticles synthesized by facile thermal decomposition of metal-Schiff base complexes
Using novel compounds for synthesis of metal oxide nanomaterials can tune their physical properties due to the associated variation in the shape, size and crystallinity. In this work, γ-Fe2O3 and Co3O4 nanoparticles were successfully prepared by a facile thermal decomposition route, employing [Fe(C32H22N4O2)]·2H2O and [Co(C16H11N3O4)].12">12H2O complexes, respectively as new precursors. The x-ray diffraction and high resolution transmission electron microscopy investigation ... Read more

Sonochemical synthesis, structural inspection and semiconductor behavior of three new nano sized Cu(II), Co(II) and Ni(II) chelates
Three novel nanosized Cu(II), Co(II) and Ni(II) complexes of imine ligand attained from the condensation of 2‐amino‐3‐hydroxypyridine and 3‐methoxysalicylaldehyde have been prepared and investigated using diverse chemical methods such as NMR, CHN analysis, conductance, IR, Spectral studies, TGA and magnetic moment measurements. The obtained data confirmed that the synthesized complexes have metal: ligand ratio of 1:1 and octahedral geometry for ... Read more